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Ni-based and Zr-based bulk metallic glasses: Changes in mechanisms of friction and wear
Zhijian Zhou  1, *@  , Sylvie Descartes  1@  , Estelle Homeyer  2@  , Aurélien Saulot  1@  , Anne Tanguy  1@  
1 : Laboratoire de Mécanique des Contacts et des Structures [Villeurbanne]
Institut National des Sciences Appliquées de Lyon, Centre National de la Recherche Scientifique, Centre National de la Recherche Scientifique : UMR5259
2 : Institut Lumière Matière [Villeurbanne]
Université Claude Bernard Lyon 1, Centre National de la Recherche Scientifique
* : Corresponding author

Metallic glasses (amorphous metal alloys) [1] obtained by thermoforming [2] are good candidates for the design of surfaces for tribological purposes. Their potential interest has been highlighted in different tribological applications [3, 4, 5]. Controlling the composition of metallic glasses allows to adjust their plastic behaviour or their sensitivity to oxidation.

Friction tests are performed using a pin-on-plane configuration, in reciprocating kinematics, at room temperature. Tests are conducted with a linear speed of 4 mm/s over 1 and 20 cycles. The planes are of metallic glasses, Nickel base and Zirconium base, presenting different Young modulus and glass transition temperature. Their amorphous nature is ascertained by X-ray diffraction (XRD). 100C6 steel pins of 70 mm radius are used as the counterface material. The initial maximum Hertz pressures are 160 and 290 MPa. Normal load is applied using dead weights. Tangential force is measured at a sampling rate of 12800 Hz using a piezoelectric sensor (underneath the sample stage). The surface features are analysed using a combination of optical interferometer, DRX, scanning electron microscopy, X-ray spectrometry. Sub-surfaces region of wear tracks are revealed by cross-sectioning. Damage and shear bands are highlighted, linked with friction coefficient evolution and on function of the metallic glasses' compositions.

[1] Ashby, A.L. Greer (2006), Metallic Glasses as structural materials, Scripta Materialia 54, pp. 321–326. [2] Gravier et al. (2012), Thermoplastic Forming of Bulk Metallic Glasses, International Journal of Applied Glass Science 3, pp. 180-187. [3] Ma et al. (2004), Resistance of Zr-based bulk metallic glass applied in bearing rollers, Materials Science and Eng. A386, pp. 326-330. [4] Ishida et al. (2007), Wear resistivity of super-precision microgear made of Ni-based metallic glass, Materials Science and Engineering A 449–451, pp. 149–154. [5] Hofmann et al. (2016), Optimizing Bulk Metallic Glasses for Robust, Highly Wear-Resistant Gears, Adv. Eng. Materials, pp. 1-10


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